Paul and Mukhopadhyay
Table 3. Correlations (r–values) between some important
ofȱcropȱgrown,ȱwaterȱuseȱandȱadditionȱofȱfertilizersȱ
physicochemical characteristics and available sulphur
(PatelȱandȱPatelȱ2008;ȱPatelȱ et al. 2011).
content of soils
Relationship of available sulphur with important
Soil characters
Available sulphur
soil physicochemical characteristics
pH
-0.02
OC
0.34**
Theȱ valuesȱ ofȱ correlationȱ co-efficientȱ presentedȱ inȱ
Total N
0.27**
theȱ Tableȱ 3,ȱ indicatedȱ aȱ significantȱ andȱ positiveȱ
correlationȱ betweenȱ availableȱ sulphurȱ andȱ organicȱ
CEC
0.04
carbonȱ (rȱ =ȱ 0.34**)ȱ andȱ itȱ wasȱ followedȱ byȱ totalȱ Nȱ
Clay
0.19*
(rȱ=ȱ0.27**)ȱcontentȱinȱsoils.ȱSoilȱtextureȱinȱtermsȱofȱ
Silt + Clay
0.24*
estimatesȱofȱclayȱ(rȱ=ȱ0.19*)ȱandȱsilt+clayȱ(rȱ=ȱ0.24*)ȱ
Oxalate-Al
0.10
alsoȱ showedȱ significantȱ andȱ positiveȱ correlationsȱ
Oxalate-Fe
0.19*
withȱavailableȱS.ȱSinceȱbothȱSȱandȱNȱareȱtheȱintegralȱ
CBD-Al
0.10
constituentsȱofȱproteinsȱinȱtheȱorganicȱmatter,ȱtheseȱ
CBD-Fe
0.24*
twoȱelementsȱuseȱtoȱmaintainȱaȱdefiniteȱN:Sȱratioȱinȱ
CBD (Al+Fe)
0.18
theȱ organicȱ matter.ȱ Hence,ȱ significantȱ andȱ positiveȱ
relationshipȱofȱavailableȱSȱwithȱtotalȱNȱandȱorganicȱ
* and ** : refer to level of significance at 0.05 and 0.01 probability
carbonȱ contentȱ wereȱ imminentȱ (Sharmaȱ andȱ Jaggiȱ
level respectively.
2001).ȱ Similarlyȱ textureȱ asȱ oneȱ ofȱ theȱ majorȱ soilȱ
43.26ȱ withȱ anȱ overallȱ meanȱ valueȱ ofȱ 24.14ȱ mgȱ kg -1
characteristicsȱhasȱdecidedȱinfluenceȱonȱSȱstatusȱinȱ
soilȱ (Tableȱ 2).ȱ However,ȱ aboutȱ 25ȱ perȱ centȱ ofȱ totalȱ soilsȱasȱtheȱamountȱofȱclayȱandȱsiltȱdeterminesȱtheȱ
soilsȱunderȱstudyȱrecordedȱtoȱhaveȱavailableȱSȱstatusȱ numberȱofȱedgeȱadsorptionȱsitesȱforȱsulphur.
underȱ mediumȱ categoryȱ andȱ almostȱ 75ȱ perȱ centȱ
Availableȱ Sȱ extractedȱ byȱ 0.15%ȱ CaCl ȱ reagentȱ thatȱ
2
underȱhighȱcategory.ȱHowever,ȱnearlyȱ11ȱperȱcentȱofȱ
exhibitedȱ goodȱ positiveȱ correlationsȱ withȱ oxalate-ȱ
totalȱsoilȱsamplesȱfoundȱtoȱcontainȱavailableȱsulphurȱ
asȱ wellȱ asȱ CBD-ȱ extractableȱ Feȱ andȱ Alȱ formsȱ andȱ
justȱonȱtheȱborderȱlineȱofȱmediumȱtoȱhighȱcategory.
combinationȱofȱCBDȱ(Al+Fe),ȱbutȱitȱwasȱsignificantȱ
AvailableȱSȱstatusȱwasȱnoticedȱ(Tableȱ2)ȱhigh,ȱaboutȱ onlyȱwithȱFeȱfractionsȱ(Oxalate-Fe:ȱrȱ=ȱ0.19*;ȱCBD-Fe:ȱ
60ȱperȱcentȱofȱtotalȱsamplesȱfromȱeachȱofȱBalorampurȱ 0.24*).ȱItȱmayȱbeȱattributedȱtoȱmoreȱretentionȱofȱSO 4 -2
andȱ Rajpurȱ soilȱ seriesȱ underȱ CoochBeharȱ districtȱ ionsȱwithȱincreaseȱinȱtheȱamountȱofȱamorphousȱandȱ
followedȱbyȱnearlyȱ40ȱperȱcentȱfromȱLotafelaȱseriesȱ crystallineȱFeȱandȱAlȱfractionsȱwhichȱwasȱfavouredȱ
underȱ CoochBehar.ȱ 30ȱ perȱ centȱ fromȱ Dhupguriȱ underȱ acidicȱ soilȱ environment.ȱ Thisȱ wasȱ furtherȱ
benchmarkȱ siteȱ underȱ Jalpaiguriȱ districtȱ wereȱ confirmedȱ inȱ theȱ presentȱ studyȱ fromȱ theȱ negativeȱ
observedȱtoȱcontainȱavailableȱSȱwithinȱtheȱmediumȱ relationshipȱobtainedȱbetweenȱtheȱsoilȱpHȱ(rȱ=ȱ-0.02)ȱ
range,ȱ whileȱ remainingȱ samplesȱ showedȱ highȱ inȱ andȱnativeȱSO 4 -Sȱcontentȱ(BasumataryȱandȱDasȱ2012).
availableȱ Sȱ status.ȱ However,ȱ 10ȱ toȱ 20ȱ perȱ centȱ ofȱ
theȱ totalȱ samplesȱ underȱ mediumȱ Sȱ availabilityȱ
Different forms of sulphur in soil
statusȱalongȱwithȱrestȱportionsȱintoȱhighȱrangeȱwereȱ
Total sulphur
notedȱ forȱ soilsȱ collectedȱ fromȱ otherȱ locations.ȱ Theȱ
observedȱ variationsȱ ofȱ sulphurȱ availabilityȱ inȱ soilsȱ TheȱtotalȱSȱcontentȱwasȱfoundȱtoȱvaryȱwidelyȱfromȱ
ofȱ differentȱ seriesȱ andȱ someȱ identifiedȱ locationsȱ 191.18ȱtoȱ530.40ȱmgȱkg -1 ȱwithȱanȱaverageȱofȱ309.21ȱ
(benchmarkȱsite)ȱtestedȱmightȱbeȱdueȱtoȱtheȱpresenceȱ mgȱkg -1 ȱ(Tableȱ4).ȱTheȱlowestȱamountȱofȱtotalȱsulphurȱ
ofȱ variableȱ proportionsȱ ofȱ differentȱ componentsȱ ofȱ wasȱ recordedȱ inȱ theȱ soilȱ sampleȱ collectedȱ fromȱ
organicȱmatterȱ(Basumataryȱ et al. 2010),ȱsoilȱandȱcropȱ Balorampurȱseries,ȱwhileȱtheȱhighestȱwasȱobservedȱ
managementȱpracticesȱsuchȱasȱintensityȱandȱnatureȱ inȱtheȱsampleȱfromȱBinnaguriȱseries.ȱMostȱofȱtheȱsoil
350